Comparison of the stability and reactivity of achiral versus chiral nonheme oxoiron(IV) complexes supported by pentadentate N5 ligands in oxygen-atom and hydrogen-atom transfer reactions

Dóra Lakk-Bogáth, G. Speier, J. Kaizer

Research output: Contribution to journalArticle

Abstract

The present work is undertaken to examine the stability, and reactivity of chiral [FeIV(N2Py2Q*)(O)]2+ (N2Py2Q* = N,N.bis(2-quinolylmethyl)-1,2-di(2-pyridyl)ethylamine) complex, along with the mechanistic details of thioanisole, benzylalcohol, and hydrocarbon oxidation in comparison with [FeIV(N4Py*)(O)]2+ (N4Py* = N,N-bis(2-pyridylmethyl)-1,2-di(2-pyridyl)ethylamine) and the related achiral FeIVO systems as a test before its utilization in an enantioselective synthesis.

Original languageEnglish
Article number107446
JournalInorganic Chemistry Communications
Volume107
DOIs
Publication statusPublished - Sep 1 2019

Fingerprint

Hydrogen
oxygen atoms
hydrogen atoms
reactivity
hydrocarbons
Hydrocarbons
Ligands
Oxygen
Atoms
Oxidation
ligands
oxidation
synthesis
ethylamine
methylphenylsulfide

Keywords

  • Biomimetic oxidation
  • C-H activation
  • Chiral iron complex
  • Kinetics
  • Oxygen-atom transfer

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

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title = "Comparison of the stability and reactivity of achiral versus chiral nonheme oxoiron(IV) complexes supported by pentadentate N5 ligands in oxygen-atom and hydrogen-atom transfer reactions",
abstract = "The present work is undertaken to examine the stability, and reactivity of chiral [FeIV(N2Py2Q*)(O)]2+ (N2Py2Q* = N,N.bis(2-quinolylmethyl)-1,2-di(2-pyridyl)ethylamine) complex, along with the mechanistic details of thioanisole, benzylalcohol, and hydrocarbon oxidation in comparison with [FeIV(N4Py*)(O)]2+ (N4Py* = N,N-bis(2-pyridylmethyl)-1,2-di(2-pyridyl)ethylamine) and the related achiral FeIVO systems as a test before its utilization in an enantioselective synthesis.",
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author = "D{\'o}ra Lakk-Bog{\'a}th and G. Speier and J. Kaizer",
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T1 - Comparison of the stability and reactivity of achiral versus chiral nonheme oxoiron(IV) complexes supported by pentadentate N5 ligands in oxygen-atom and hydrogen-atom transfer reactions

AU - Lakk-Bogáth, Dóra

AU - Speier, G.

AU - Kaizer, J.

PY - 2019/9/1

Y1 - 2019/9/1

N2 - The present work is undertaken to examine the stability, and reactivity of chiral [FeIV(N2Py2Q*)(O)]2+ (N2Py2Q* = N,N.bis(2-quinolylmethyl)-1,2-di(2-pyridyl)ethylamine) complex, along with the mechanistic details of thioanisole, benzylalcohol, and hydrocarbon oxidation in comparison with [FeIV(N4Py*)(O)]2+ (N4Py* = N,N-bis(2-pyridylmethyl)-1,2-di(2-pyridyl)ethylamine) and the related achiral FeIVO systems as a test before its utilization in an enantioselective synthesis.

AB - The present work is undertaken to examine the stability, and reactivity of chiral [FeIV(N2Py2Q*)(O)]2+ (N2Py2Q* = N,N.bis(2-quinolylmethyl)-1,2-di(2-pyridyl)ethylamine) complex, along with the mechanistic details of thioanisole, benzylalcohol, and hydrocarbon oxidation in comparison with [FeIV(N4Py*)(O)]2+ (N4Py* = N,N-bis(2-pyridylmethyl)-1,2-di(2-pyridyl)ethylamine) and the related achiral FeIVO systems as a test before its utilization in an enantioselective synthesis.

KW - Biomimetic oxidation

KW - C-H activation

KW - Chiral iron complex

KW - Kinetics

KW - Oxygen-atom transfer

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