Comparative study of different cyanide-selective air-gap electrodes

J. Fligier, M. Gratzl, G. Nagy, E. Pungor

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The characteristics of four solid-state cyanide-selective air-gap electrodes are described. When a minute volume of dicyanoargentate(I) solution was used as electrolyte, the double-Nernstian response to cyanide concentration was obtained only with the sensors based on silver or silver sulphide. Sensors based on silver iodide or a silver sulphide/iodide mixture displayed the normal Nernstian character shown by cyanide-selective electrodes dipped in solution. A theoretical explanation of the results involves the relevant equilibrium equations and the mass balance.

Original languageEnglish
Pages (from-to)263-269
Number of pages7
JournalAnalytica Chimica Acta
Volume134
Issue numberC
DOIs
Publication statusPublished - Jan 1 1982

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Environmental Chemistry
  • Spectroscopy

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