Comparative study of anion-involvement in redox transformations of poly(o-phenylene-diamine) (PPD) films by a coupled electrochemical and radiometric technique

K. Martinusz, G. Inzelt, G. Horányi

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

The sorption of H2PO- 4 , HSO- 4 and Cl- ions in poly(o-phenylene-diamine) (PPD) film was studied and compared by the radiotracer technique using 35S, 32P and 36Cl isotopes for labelling. It was found that the anion sorption in both oxidized and reduced films depends on pH, i.e. on the protonation of the film; however, the protonation and anion sorption is not an essential condition for the occurrence of the redox process. Results furnished by differential volt-radiometric measurements advocate in the favour of the assumption that the reduction of film results in the formation of three or four types of centre with different behaviour with respect to the protonation and anion sorption. It was demonstrated that PPD films are very selective for the sorption of HSO- 4(SO2- 4) ions in the presence of a great excess of other anions.

Original languageEnglish
Pages (from-to)143-148
Number of pages6
JournalJournal of Electroanalytical Chemistry
Volume404
Issue number1
DOIs
Publication statusPublished - Mar 7 1996

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Diamines
Tuberculin
Anions
Sorption
Negative ions
Protonation
Ions
Isotopes
Labeling
Oxidation-Reduction

Keywords

  • Ion sorption
  • Poly(o-phenylene-diamine)
  • Redox transformation
  • Volt-radiometric measurements

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Analytical Chemistry
  • Electrochemistry

Cite this

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title = "Comparative study of anion-involvement in redox transformations of poly(o-phenylene-diamine) (PPD) films by a coupled electrochemical and radiometric technique",
abstract = "The sorption of H2PO- 4 , HSO- 4 and Cl- ions in poly(o-phenylene-diamine) (PPD) film was studied and compared by the radiotracer technique using 35S, 32P and 36Cl isotopes for labelling. It was found that the anion sorption in both oxidized and reduced films depends on pH, i.e. on the protonation of the film; however, the protonation and anion sorption is not an essential condition for the occurrence of the redox process. Results furnished by differential volt-radiometric measurements advocate in the favour of the assumption that the reduction of film results in the formation of three or four types of centre with different behaviour with respect to the protonation and anion sorption. It was demonstrated that PPD films are very selective for the sorption of HSO- 4(SO2- 4) ions in the presence of a great excess of other anions.",
keywords = "Ion sorption, Poly(o-phenylene-diamine), Redox transformation, Volt-radiometric measurements",
author = "K. Martinusz and G. Inzelt and G. Hor{\'a}nyi",
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T1 - Comparative study of anion-involvement in redox transformations of poly(o-phenylene-diamine) (PPD) films by a coupled electrochemical and radiometric technique

AU - Martinusz, K.

AU - Inzelt, G.

AU - Horányi, G.

PY - 1996/3/7

Y1 - 1996/3/7

N2 - The sorption of H2PO- 4 , HSO- 4 and Cl- ions in poly(o-phenylene-diamine) (PPD) film was studied and compared by the radiotracer technique using 35S, 32P and 36Cl isotopes for labelling. It was found that the anion sorption in both oxidized and reduced films depends on pH, i.e. on the protonation of the film; however, the protonation and anion sorption is not an essential condition for the occurrence of the redox process. Results furnished by differential volt-radiometric measurements advocate in the favour of the assumption that the reduction of film results in the formation of three or four types of centre with different behaviour with respect to the protonation and anion sorption. It was demonstrated that PPD films are very selective for the sorption of HSO- 4(SO2- 4) ions in the presence of a great excess of other anions.

AB - The sorption of H2PO- 4 , HSO- 4 and Cl- ions in poly(o-phenylene-diamine) (PPD) film was studied and compared by the radiotracer technique using 35S, 32P and 36Cl isotopes for labelling. It was found that the anion sorption in both oxidized and reduced films depends on pH, i.e. on the protonation of the film; however, the protonation and anion sorption is not an essential condition for the occurrence of the redox process. Results furnished by differential volt-radiometric measurements advocate in the favour of the assumption that the reduction of film results in the formation of three or four types of centre with different behaviour with respect to the protonation and anion sorption. It was demonstrated that PPD films are very selective for the sorption of HSO- 4(SO2- 4) ions in the presence of a great excess of other anions.

KW - Ion sorption

KW - Poly(o-phenylene-diamine)

KW - Redox transformation

KW - Volt-radiometric measurements

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