The ultraviolet spectroscopic and temperature-dependent kinetic behaviour o f some A-alkyl-A-phenyl-carbamic acid trimethylsilyl esters were studied. The change o f wavelength of the 1 L a bands and their solvent dependence was interpreted by the different steric hindrance of the alkyl group. For the solvolysis o f esters with isopropanol the activation parameters were determined. Correlations between the experimental data are also discussed.
|Number of pages||12|
|Journal||ACH - Models in Chemistry|
|Publication status||Published - Jan 1 1999|
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