Comment on "The Role of Concentration Dependent Static Permittivity of Electrolyte Solutions in the Debye-Hückel Theory"

Mónika Valiskó, D. Boda

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Researchers comment on the role of concentration dependent static permittivity of electrolyte solutions in the Debye-Hückel Theory. Debye and Hückel have divided the thermodynamic functions into two parts representing interionic and ion-water interactions denoted by numbers 1 and 2. These terms clearly correspond to the (ion-ion (II) and (ion-water (IW) terms in the excess chemical potential introduced in the II + IW model. The researchers show in their comment that the IW term is equivalent to the solvation term of Shilov and Lyashchenko. They also show that the Born radii can and should be used in it instead of the Pauling radii for conducting the investigations.

Original languageEnglish
Pages (from-to)14332-14336
Number of pages5
JournalJournal of Physical Chemistry B
Volume119
Issue number44
DOIs
Publication statusPublished - 2015

Fingerprint

Electrolytes
Permittivity
electrolytes
Ions
permittivity
ions
Water
water
radii
Chemical potential
Solvation
solvation
Thermodynamics
conduction
thermodynamics

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Surfaces, Coatings and Films

Cite this

Comment on "The Role of Concentration Dependent Static Permittivity of Electrolyte Solutions in the Debye-Hückel Theory". / Valiskó, Mónika; Boda, D.

In: Journal of Physical Chemistry B, Vol. 119, No. 44, 2015, p. 14332-14336.

Research output: Contribution to journalArticle

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