Combined electron diffraction/mass-spectrometric investigation of the molecular structure of germanium dichloride

Gy Schultz, J. Tremmel, I. Hargittai, I. Berecz, S. Bohátka, N. D. Kagramanov, A. K. Maltsev, O. M. Nefedov

Research output: Contribution to journalArticle

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Abstract

Germanium dichloride was produced by reaction of Ge + GeCl4 at 660°C in a combined electron diffraction/quadrupole mass-spectrometric experiment. The structure of germanium dichloride can be characterized by the following parameters: ra (GeCl): 2.183 (4) Å, l(GeCl): 0.080 (2) Å, ∠ClGeCl: 100.3(4)°, l(ClċCl): 0.166 (4) Å. The geometrical variations observed in Group IV dihalides are consistent with the VSEPR model, and with considerations based on non-bonded interactions.

Original languageEnglish
Pages (from-to)207-214
Number of pages8
JournalJournal of Molecular Structure
Volume55
Issue numberC
DOIs
Publication statusPublished - 1979

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Germanium
dichlorides
Molecular Structure
Electron diffraction
Molecular structure
germanium
molecular structure
electron diffraction
Electrons
quadrupoles
Experiments
interactions

ASJC Scopus subject areas

  • Structural Biology
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Materials Science (miscellaneous)
  • Atomic and Molecular Physics, and Optics

Cite this

Combined electron diffraction/mass-spectrometric investigation of the molecular structure of germanium dichloride. / Schultz, Gy; Tremmel, J.; Hargittai, I.; Berecz, I.; Bohátka, S.; Kagramanov, N. D.; Maltsev, A. K.; Nefedov, O. M.

In: Journal of Molecular Structure, Vol. 55, No. C, 1979, p. 207-214.

Research output: Contribution to journalArticle

Schultz, Gy ; Tremmel, J. ; Hargittai, I. ; Berecz, I. ; Bohátka, S. ; Kagramanov, N. D. ; Maltsev, A. K. ; Nefedov, O. M. / Combined electron diffraction/mass-spectrometric investigation of the molecular structure of germanium dichloride. In: Journal of Molecular Structure. 1979 ; Vol. 55, No. C. pp. 207-214.
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abstract = "Germanium dichloride was produced by reaction of Ge + GeCl4 at 660°C in a combined electron diffraction/quadrupole mass-spectrometric experiment. The structure of germanium dichloride can be characterized by the following parameters: ra (GeCl): 2.183 (4) {\AA}, l(GeCl): 0.080 (2) {\AA}, ∠ClGeCl: 100.3(4)°, l(ClċCl): 0.166 (4) {\AA}. The geometrical variations observed in Group IV dihalides are consistent with the VSEPR model, and with considerations based on non-bonded interactions.",
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AU - Tremmel, J.

AU - Hargittai, I.

AU - Berecz, I.

AU - Bohátka, S.

AU - Kagramanov, N. D.

AU - Maltsev, A. K.

AU - Nefedov, O. M.

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