Colloid chemical characterisation of layered titanates, their hydrophobic derivatives and self-assembled films

Szilvia Papp, I. Dékány

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Na2Ti3O7, with layered structure, was prepared from a 1:3 molar mixture of powdered Na2 CO3 and TiO2 by heating at 800 °C for h. The Na+ ions were exchanged for H+ ions by hydrochloric acid treatment; next, n-butylamine, n-octylamine, n-decylamine or n-dodecylamine were incorporated at pH=3.6-3.8. It was proven by XRD measurements that, as the length of the alkyl chain of the amines was increased, smaller amounts of amines were intercalated under identical conditions. H2Ti3O7 samples dispersed in liquids of various compositions and polarities were used for the preparation of self-assembled titanate/polymer films for further sensor applications. Titanates, their composites with alkyl amines and the self-assembled hybrid structures were characterized by X-ray diffraction, thermoanalytical, optical, electron and atomic force microscopic measurements.

Original languageEnglish
Pages (from-to)1116-1122
Number of pages7
JournalColloid & Polymer Science
Volume283
Issue number10
DOIs
Publication statusPublished - Jul 2005

Fingerprint

titanates
Colloids
Amines
colloids
amines
Derivatives
Ions
hybrid structures
Hydrochloric Acid
hydrochloric acid
Hydrochloric acid
Polymer films
polarity
ions
Heating
X ray diffraction
preparation
heating
composite materials
Electrons

Keywords

  • Hybrid films
  • Self-assembling
  • Titanate/polymer nanocomposites
  • Trititanate

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Polymers and Plastics
  • Materials Chemistry
  • Colloid and Surface Chemistry

Cite this

Colloid chemical characterisation of layered titanates, their hydrophobic derivatives and self-assembled films. / Papp, Szilvia; Dékány, I.

In: Colloid & Polymer Science, Vol. 283, No. 10, 07.2005, p. 1116-1122.

Research output: Contribution to journalArticle

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