Collisional energy transfer in the two-channel decomposition of 1,1,2,2-tetrafluorocyclobutane and 1-methyl-2,2,3,3-tetrafluorocyclobutane, II. Gas/wall collisions

L. Zalotai, T. Turányi, T. Bérces, F. Márta

Research output: Contribution to journalArticle

Abstract

The efficiency of gas/wall vibrational energy transfer has been studied over the temperature range 800-1100 K by the "variable encounter" method. The average energies transferred per deactiviting collisions with the wall were determined at 800 K to be 3200 cm-1 and 2900 cm-1 for the 1,1,2,2-tetrafluorocyclobutane (TFCB) and 1-methyl-2,2,3,3-tetrafluorocyclobutane (MTFCB) molecules, respectively. This energy increased strongly with decreasing temperature. A comparison is made of <ΔE′> with previous results for related molecules.

Original languageEnglish
Pages (from-to)409-414
Number of pages6
JournalReaction Kinetics & Catalysis Letters
Volume51
Issue number2
DOIs
Publication statusPublished - Dec 1 1993

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ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

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