Collisional energy transfer in the decomposition of 2-methyloxetane and 3-methyloxetane, II. Gas/wall collisions

L. Zalotai, T. Bérces, F. Márta

Research output: Contribution to journalArticle

Abstract

The variable encounter method has been applied for the study of gas/wall vibrational energy transfer in the thermal decomposition of 2-methyloxetane and 3-methyloxetane. The average probability of reaction per collision was deduced from the data and was compared with stochastic calculations based on gaussian and exponential energy transfer probability models. The gaussian model fits the experimental data best. Using this model, the average down step energies were 2600 and 2690 cm-1 for 2-methyloxetane and 3-methyloxetane, respectively, at 750 K, and they decreased with increasing temperature.

Original languageEnglish
Pages (from-to)87-93
Number of pages7
JournalReaction Kinetics and Catalysis Letters
Volume42
Issue number1
DOIs
Publication statusPublished - Jul 1990

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Energy transfer
Gases
energy transfer
Decomposition
decomposition
collisions
gases
encounters
thermal decomposition
Pyrolysis
Temperature
temperature
energy

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Catalysis

Cite this

Collisional energy transfer in the decomposition of 2-methyloxetane and 3-methyloxetane, II. Gas/wall collisions. / Zalotai, L.; Bérces, T.; Márta, F.

In: Reaction Kinetics and Catalysis Letters, Vol. 42, No. 1, 07.1990, p. 87-93.

Research output: Contribution to journalArticle

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