Cluster Synthesis via Inorganic Diazo Compounds. The Synthesis and Crystal and Molecular Structure of H2IrOs3(μ-Cl)(μ-CO)(CO)9PPh3

Richard D. Adams, István T. Horváth, Brigitte E. Segmüller

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11 Citations (Scopus)

Abstract

The reaction of Ir(N2)(PPh3)2Cl with H2Os3(C-O)10 has yielded the mixed metal cluster complex H2IrOs3(μ-Cl)(μ-CO)(CO)9PPh3, I, in 15% yield. I has been characterized by IR, 1H NMR, elemental, and single-crystal X-ray diffraction analyses.

Original languageEnglish
Pages (from-to)1537-1538
Number of pages2
JournalOrganometallics
Volume1
Issue number11
DOIs
Publication statusPublished - Jan 1 1982

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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