Circular Dichroism, XC. CD of 1‐Cyano Derivatives of Pyranoses

IstváN Farkas, L. Somsák, Günther Snatzke

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Saturated nitriles give no band in the accessible wavelength range but do so when OAc or Br are in geminal position to CN. Is the latter combination present at C‐1 then (R) configuration leads to a positive CD between 230 and 240 nm. The Cotton effect of 1‐cyanoglycals follows the same rule as that found for the parent glycals.

Original languageEnglish
Pages (from-to)599-600
Number of pages2
JournalLiebigs Annalen der Chemie
Volume1989
Issue number6
DOIs
Publication statusPublished - 1989

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Keywords

  • Cotton effect
  • Glycals, 1‐cyano
  • Sugars, 1‐bromo‐1‐cyano

ASJC Scopus subject areas

  • Medicine(all)

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