CH4 dry reforming with CO2: Characterization of surface carbon species formed on CeOx-ZrOy based ni, Ni-Co and Ni-Rh catalysts

L. Guczi, G. Stefler, Alain Kiennemann, Agnieszka Pietraszek

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Ce-Zr oxide based metal catalysts were prepared by sol-gel or impregnation method and its structure, activity, and the different carbonaceous species formed during the CH4 dry reforming with CO2 were studied. The catalytic tests showed the temperature dependence on catalytic activity for CeZrNi and CeZrNiMe based catalysts. CH4 conversion was lower than CO2 due to the presence of reverse water gas-shift reaction occurring simultaneously with CO2 reforming of CH4. The highest activity in both CO2 and CH4 conversion was observed over catalyst where the part of Ni was substituted by Rh. The Ni/CeZr catalyst with Ni impregnated on it was lower than CeZrNiRh but higher than sol-gel prepared and CeZrNiCo. This is an abstract of a paper presented at the 2010 Spring National Meeting (San Antonio, TX 3/21-25/2010).

Original languageEnglish
Title of host publication10AIChE - 2010 AIChE Spring Meeting and 6th Global Congress on Process Safety
Publication statusPublished - 2010
Event2010 AIChE Spring Meeting and 6th Global Congress on Process Safety, 10AIChE - San Antonio, TX, United States
Duration: Mar 21 2010Mar 25 2010

Other

Other2010 AIChE Spring Meeting and 6th Global Congress on Process Safety, 10AIChE
CountryUnited States
CitySan Antonio, TX
Period3/21/103/25/10

Fingerprint

Reforming reactions
Carbon
activity structure
Catalysts
Sol-gels
water
Water gas shift
Impregnation
Oxides
Catalyst activity
Metals
Temperature

ASJC Scopus subject areas

  • Chemical Health and Safety
  • Safety, Risk, Reliability and Quality
  • Safety Research

Cite this

Guczi, L., Stefler, G., Kiennemann, A., & Pietraszek, A. (2010). CH4 dry reforming with CO2: Characterization of surface carbon species formed on CeOx-ZrOy based ni, Ni-Co and Ni-Rh catalysts. In 10AIChE - 2010 AIChE Spring Meeting and 6th Global Congress on Process Safety

CH4 dry reforming with CO2 : Characterization of surface carbon species formed on CeOx-ZrOy based ni, Ni-Co and Ni-Rh catalysts. / Guczi, L.; Stefler, G.; Kiennemann, Alain; Pietraszek, Agnieszka.

10AIChE - 2010 AIChE Spring Meeting and 6th Global Congress on Process Safety. 2010.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Guczi, L, Stefler, G, Kiennemann, A & Pietraszek, A 2010, CH4 dry reforming with CO2: Characterization of surface carbon species formed on CeOx-ZrOy based ni, Ni-Co and Ni-Rh catalysts. in 10AIChE - 2010 AIChE Spring Meeting and 6th Global Congress on Process Safety. 2010 AIChE Spring Meeting and 6th Global Congress on Process Safety, 10AIChE, San Antonio, TX, United States, 3/21/10.
Guczi L, Stefler G, Kiennemann A, Pietraszek A. CH4 dry reforming with CO2: Characterization of surface carbon species formed on CeOx-ZrOy based ni, Ni-Co and Ni-Rh catalysts. In 10AIChE - 2010 AIChE Spring Meeting and 6th Global Congress on Process Safety. 2010
Guczi, L. ; Stefler, G. ; Kiennemann, Alain ; Pietraszek, Agnieszka. / CH4 dry reforming with CO2 : Characterization of surface carbon species formed on CeOx-ZrOy based ni, Ni-Co and Ni-Rh catalysts. 10AIChE - 2010 AIChE Spring Meeting and 6th Global Congress on Process Safety. 2010.
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