Chlorination of V2O5 by CCl4. The proposed reaction mechanism

G. Mink, I. Bertóti, C. Battistoni, T. Székely

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Initial stage of the reaction of CCl4 with V2O5 has been studied by MS and XPS techniques. According to the proposed mechanism dissociatively chemisorbed CCl4 transforms to CO2 via adsorbed COCl2, while surface vanadium atoms involved are gaining step by step two chlorine atoms before the formation of the volatile end-product VOCl3.

Original languageEnglish
Pages (from-to)39-45
Number of pages7
JournalReaction Kinetics and Catalysis Letters
Volume27
Issue number1
DOIs
Publication statusPublished - Mar 1 1985

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

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