Chlorination of V2O5 by CCl4. Adsorption and steady state reaction

G. Mink, I. Bertóti, T. Székely

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The adsorption of CCl4 on V2O5 as well as the steady state kinetics of the chlorination reaction in this system have been studied by volumetric and thermogravimetric methods. Though the adsorption observable below 420 K is of physical character, it can be suggested that an unmeasurable, dissociative type adsorption also occurs. The apparent activation energy of the chlorination process is 77±5 kJ mol-1, while the reaction order is 0.5 in CCl4.

Original languageEnglish
Pages (from-to)33-38
Number of pages6
JournalReaction Kinetics and Catalysis Letters
Volume27
Issue number1
DOIs
Publication statusPublished - Mar 1 1985

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Chlorination of V<sub>2</sub>O<sub>5</sub> by CCl<sub>4</sub>. Adsorption and steady state reaction'. Together they form a unique fingerprint.

  • Cite this