Chlorination of V2O5 by CCl4. Adsorption and steady state reaction

G. Mink, I. Bertóti, T. Székely

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The adsorption of CCl4 on V2O5 as well as the steady state kinetics of the chlorination reaction in this system have been studied by volumetric and thermogravimetric methods. Though the adsorption observable below 420 K is of physical character, it can be suggested that an unmeasurable, dissociative type adsorption also occurs. The apparent activation energy of the chlorination process is 77±5 kJ mol-1, while the reaction order is 0.5 in CCl4.

Original languageEnglish
Pages (from-to)33-38
Number of pages6
JournalReaction Kinetics and Catalysis Letters
Volume27
Issue number1
DOIs
Publication statusPublished - Mar 1985

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chlorination
Chlorination
Adsorption
adsorption
Activation energy
activation energy
Kinetics
kinetics
vanadium pentoxide

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Catalysis

Cite this

Chlorination of V2O5 by CCl4. Adsorption and steady state reaction. / Mink, G.; Bertóti, I.; Székely, T.

In: Reaction Kinetics and Catalysis Letters, Vol. 27, No. 1, 03.1985, p. 33-38.

Research output: Contribution to journalArticle

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