Chemistry of mixed ligand complexes. VII. The Mössbauer investigation of cyclopentadienyl iron carbonyl mixed complexes

K. Burger, L. Korecz, P. Mag, U. Belluco, L. Busetto

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Abstract

The Mössbauer parameters of (C5H5)Fe(CO)2X mixed complexes were determined, where X = CS, CO, CN-, P(C6H5)3, NCO-, NCS-, Br-. The Mössbauer isomer shifts indicated the order of π-acceptor ability of these ligands and the partial isomer shift parameters of the ligands could be calculated. The quadrupole splittings gave information on the formal coordination number of iron in the complexes.

Original languageEnglish
Pages (from-to)362-364
Number of pages3
JournalInorganica Chimica Acta
Volume5
Issue numberC
DOIs
Publication statusPublished - Mar 1971

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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