Chemistry of mixed ligand complexes. VII. The Mössbauer investigation of cyclopentadienyl iron carbonyl mixed complexes

K. Burger, L. Korecz, P. Mag, U. Belluco, L. Busetto

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Abstract

The Mössbauer parameters of (C5H5)Fe(CO)2X mixed complexes were determined, where X = CS, CO, CN-, P(C6H5)3, NCO-, NCS-, Br-. The Mössbauer isomer shifts indicated the order of π-acceptor ability of these ligands and the partial isomer shift parameters of the ligands could be calculated. The quadrupole splittings gave information on the formal coordination number of iron in the complexes.

Original languageEnglish
Pages (from-to)362-364
Number of pages3
JournalInorganica Chimica Acta
Volume5
Issue numberC
DOIs
Publication statusPublished - 1971

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Carbon Monoxide
Isomers
isomers
Iron
Ligands
chemistry
iron
ligands
shift
coordination number
quadrupoles

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Chemistry of mixed ligand complexes. VII. The Mössbauer investigation of cyclopentadienyl iron carbonyl mixed complexes. / Burger, K.; Korecz, L.; Mag, P.; Belluco, U.; Busetto, L.

In: Inorganica Chimica Acta, Vol. 5, No. C, 1971, p. 362-364.

Research output: Contribution to journalArticle

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AU - Mag, P.

AU - Belluco, U.

AU - Busetto, L.

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