Chemical reactions in fast atom bombardment mass spectrometry

K. Vékey, Luigi F. Zerilli

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Examples of various chemical reactions occurring in the matrix or in the selvedge region in fast atom bombardment (FAB) mass spectrometry are discussed. These are categorized as oxidations and reductions; substitutions; clusterings and additions; and sample decomposition or transformation. Some reactions observed showed significant time behaviour and in one case it was possible to determine rate constants. These data suggest that chemical reactions can be accelerated significantly by fast atom bombardment.

Original languageEnglish
Pages (from-to)939-944
Number of pages6
JournalOrganic Mass Spectrometry
Issue number11
Publication statusPublished - 1991


ASJC Scopus subject areas

  • Biochemistry
  • Molecular Medicine
  • Instrumentation

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