Chain end functionalization of polystyrene obtained by quasiliving atom transfer radical polymerization

B. Iván, Tamás Fánagy

Research output: Chapter in Book/Report/Conference proceedingChapter

5 Citations (Scopus)

Abstract

Polystyrene oligomers with exact 1-chloro-1-phenylethyl terminal functionality were prepared in high yields by quasiliving atom transfer radical polymerization (ATRP) without detectable side reactions, such as recombination. The resulting endgroup was quantitatively converted to allyl chain ends with allyltrimethylsilane in the presence of TiCl4 under quasiliving carbocationic polymerization conditions. It was found that the order of addition of the reacting compounds is the determining factor for obtaining the desired derivatization.

Original languageEnglish
Title of host publicationAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
PublisherACS
Pages356-357
Number of pages2
Volume40
Edition2
Publication statusPublished - Aug 1999

Fingerprint

Atom transfer radical polymerization
Polystyrenes
Oligomers
Polymerization
allyltrimethylsilane
titanium tetrachloride

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Iván, B., & Fánagy, T. (1999). Chain end functionalization of polystyrene obtained by quasiliving atom transfer radical polymerization. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (2 ed., Vol. 40, pp. 356-357). ACS.

Chain end functionalization of polystyrene obtained by quasiliving atom transfer radical polymerization. / Iván, B.; Fánagy, Tamás.

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 40 2. ed. ACS, 1999. p. 356-357.

Research output: Chapter in Book/Report/Conference proceedingChapter

Iván, B & Fánagy, T 1999, Chain end functionalization of polystyrene obtained by quasiliving atom transfer radical polymerization. in American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 2 edn, vol. 40, ACS, pp. 356-357.
Iván B, Fánagy T. Chain end functionalization of polystyrene obtained by quasiliving atom transfer radical polymerization. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 2 ed. Vol. 40. ACS. 1999. p. 356-357
Iván, B. ; Fánagy, Tamás. / Chain end functionalization of polystyrene obtained by quasiliving atom transfer radical polymerization. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 40 2. ed. ACS, 1999. pp. 356-357
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