Catalytic transfer hydrogenation and hydrogenolysis in ionic liquids with Pd/MgLa mixed oxide and Pd/MgAl hydrotalcite as recyclable catalysts

Zoltán Baán, Attila Potor, Agnieszka Cwik, Z. Hell, G. Keglevich, Zoltán Finta, I. Hermecz

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A new Pd/MgLa mixed oxide and the known Pd/MgAl hydrotalcite catalysts were applied and recycled successfully in catalytic transfer hydrogenation reactions in ionic liquids. Some α,β-unsaturated carboxylic acid derivatives were hydrogenated in excellent yields. The catalysts were recycled without significant loss of activity. Besides that, a number of halogenated aromatic compounds were dehalogenated under similar catalytic transfer conditions.

Original languageEnglish
Pages (from-to)1601-1609
Number of pages9
JournalSynthetic Communications
Volume38
Issue number10
DOIs
Publication statusPublished - Jan 2008

Fingerprint

hydrotalcite
Ionic Liquids
Hydrogenolysis
Oxides
Hydrogenation
Catalysts
Aromatic compounds
Carboxylic Acids
Derivatives

Keywords

  • Hydrotalcite
  • Ionic liquids
  • Palladium
  • Transfer hydrogenation

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Catalytic transfer hydrogenation and hydrogenolysis in ionic liquids with Pd/MgLa mixed oxide and Pd/MgAl hydrotalcite as recyclable catalysts. / Baán, Zoltán; Potor, Attila; Cwik, Agnieszka; Hell, Z.; Keglevich, G.; Finta, Zoltán; Hermecz, I.

In: Synthetic Communications, Vol. 38, No. 10, 01.2008, p. 1601-1609.

Research output: Contribution to journalArticle

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AU - Keglevich, G.

AU - Finta, Zoltán

AU - Hermecz, I.

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