Catalytic hydrosilylation of carbon monoxide with cobalt carbonyls

Attila Sisak, László Markó, Zoltán Angyalosy, F. Ungváry

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The hydrosilylation of carbon monoxide with cobalt carbonyls under relatively mild conditions resulted in a Fischer-Tropsch-analogous reductive coupling of CO. Alkyl silyl ethers, 1,2-bis(silyloxy)-1-alkenes and higher molecular weight compounds with at least three silyloxy groups were also formed, each of these containing up to seven carbon atoms derived from CO and for the most part having a linear structure. A (silyloxycarbyne)cobalt complex was postulated as the key intermediate.

Original languageEnglish
Pages (from-to)131-134
Number of pages4
JournalInorganica Chimica Acta
Volume222
Issue number1-2
DOIs
Publication statusPublished - 1994

Fingerprint

Hydrosilylation
Carbon Monoxide
Cobalt
Carbon monoxide
carbon monoxide
cobalt
alkenes
Olefins
Ethers
molecular weight
ethers
Molecular weight
Alkenes
Atoms
Carbon
carbon
Molecular Weight
atoms

Keywords

  • Carbonyl complexes
  • Catalysis
  • Cobalt complexes
  • Hydrosilylation

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Catalytic hydrosilylation of carbon monoxide with cobalt carbonyls. / Sisak, Attila; Markó, László; Angyalosy, Zoltán; Ungváry, F.

In: Inorganica Chimica Acta, Vol. 222, No. 1-2, 1994, p. 131-134.

Research output: Contribution to journalArticle

Sisak, Attila ; Markó, László ; Angyalosy, Zoltán ; Ungváry, F. / Catalytic hydrosilylation of carbon monoxide with cobalt carbonyls. In: Inorganica Chimica Acta. 1994 ; Vol. 222, No. 1-2. pp. 131-134.
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