Catalytic and stoichiometric flavanone oxidation mediated by nonheme oxoiron(iv) complexes as flavone synthase mimics: Kinetic, mechanistic and computational studies

Ramona Turcas, Balázs Kripli, Amr A.A. Attia, Dóra Lakk-Bogáth, G. Speier, Michel Giorgi, Radu Silaghi-Dumitrescu, J. Kaizer

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The present study describes the first example of the stoichiometric and catalytic oxidation of flavanone by synthetic nonheme oxoiron(iv) complexes and their precursor iron(ii) complexes with m-CPBA as the terminal oxidant. These models, including detailed kinetic, mechanistic and computational studies, may serve as the biomimics of flavone synthase (FS) enzymes.

Original languageEnglish
Pages (from-to)14416-14420
Number of pages5
JournalDalton Transactions
Volume47
Issue number41
DOIs
Publication statusPublished - Jan 1 2018

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flavone
Catalytic oxidation
Oxidants
Iron
Oxidation
Kinetics
Enzymes
flavanone
3-chloroperbenzoic acid

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Catalytic and stoichiometric flavanone oxidation mediated by nonheme oxoiron(iv) complexes as flavone synthase mimics : Kinetic, mechanistic and computational studies. / Turcas, Ramona; Kripli, Balázs; Attia, Amr A.A.; Lakk-Bogáth, Dóra; Speier, G.; Giorgi, Michel; Silaghi-Dumitrescu, Radu; Kaizer, J.

In: Dalton Transactions, Vol. 47, No. 41, 01.01.2018, p. 14416-14420.

Research output: Contribution to journalArticle

Turcas, Ramona ; Kripli, Balázs ; Attia, Amr A.A. ; Lakk-Bogáth, Dóra ; Speier, G. ; Giorgi, Michel ; Silaghi-Dumitrescu, Radu ; Kaizer, J. / Catalytic and stoichiometric flavanone oxidation mediated by nonheme oxoiron(iv) complexes as flavone synthase mimics : Kinetic, mechanistic and computational studies. In: Dalton Transactions. 2018 ; Vol. 47, No. 41. pp. 14416-14420.
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