Breakdown of organic mercury compounds by hydrochloric acid-permanganate or bromine monochloride solution for the determination of mercury by cold-vapour atomic absorption spectrometry

O. Szakács, A. Lásztity, Zs Horváth

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35 Citations (Scopus)

Abstract

Hydrochloric acid-potassium permanganate and bromine monochloride are examined for the decomposition of methylmercury(II) chloride, Ceresan, phenylmercury(II) borate and thiomersal added to waters. Both procedures give quantitative recovery of mercury. Bromine monochloride has many advantages: blanks are low, the limit of detection (3σ) is 0.06 μg Hg l-1, routine work is simplified because only two reagents are needed and the reaction time is 5-10 min. The reagent also acts as a preservative. Common contaminants (chloride, bromide, sulphide, alcohols, benzene) do not interfere.

Original languageEnglish
Pages (from-to)219-224
Number of pages6
JournalAnalytica Chimica Acta
Volume121
Issue numberC
DOIs
Publication statusPublished - Dec 1 1980

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ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Environmental Chemistry
  • Spectroscopy

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