Bis(dibenzo[c.e][1,2]oxaphosphorino)dichloroplatinum complexes

György Keglevich, Andrea Kerényi, Helga Szelke, Timea Imre

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Reaction of a series of P-amino and P-cycloalkoxy dibenzo[c.e][1,2] oxaphosphorines (1), (3) and (5) with cis-bis(benzonitrile)dichloroplatinum(II) afforded the title bis(dibenzooxaphosphorino) complexes (2), (4) and (6), respectively. In the case of chiral P-substituents, the complexes (4) and (6) were obtained in homo and heterochiral forms. Stereospecific 1 J(195Pt-P) couplings found in the 31P-n.m.r. spectra of the products (2), (4) and (6) suggested the cis orientation of the identical substituents.

Original languageEnglish
Pages (from-to)306-309
Number of pages4
JournalTransition Metal Chemistry
Volume31
Issue number3
DOIs
Publication statusPublished - Apr 1 2006

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Metals and Alloys
  • Materials Chemistry

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