Bis(dibenzo[c.e][1,2]oxaphosphorino)dichloroplatinum complexes

G. Keglevich, Andrea Kerényi, Helga Szelke, T. Imre

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Abstract

Reaction of a series of P-amino and P-cycloalkoxy dibenzo[c.e][1,2] oxaphosphorines (1), (3) and (5) with cis-bis(benzonitrile)dichloroplatinum(II) afforded the title bis(dibenzooxaphosphorino) complexes (2), (4) and (6), respectively. In the case of chiral P-substituents, the complexes (4) and (6) were obtained in homo and heterochiral forms. Stereospecific 1 J(195Pt-P) couplings found in the 31P-n.m.r. spectra of the products (2), (4) and (6) suggested the cis orientation of the identical substituents.

Original languageEnglish
Pages (from-to)306-309
Number of pages4
JournalTransition Metal Chemistry
Volume31
Issue number3
DOIs
Publication statusPublished - Apr 2006

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ASJC Scopus subject areas

  • Inorganic Chemistry

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Bis(dibenzo[c.e][1,2]oxaphosphorino)dichloroplatinum complexes. / Keglevich, G.; Kerényi, Andrea; Szelke, Helga; Imre, T.

In: Transition Metal Chemistry, Vol. 31, No. 3, 04.2006, p. 306-309.

Research output: Contribution to journalArticle

Keglevich, G. ; Kerényi, Andrea ; Szelke, Helga ; Imre, T. / Bis(dibenzo[c.e][1,2]oxaphosphorino)dichloroplatinum complexes. In: Transition Metal Chemistry. 2006 ; Vol. 31, No. 3. pp. 306-309.
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