Biradical intermediates in 7.6 eV photon-induced isomerization of liquid alkylcyclohexanes

L. Wojnárovits, L. Kozári, C. S. Keszei, G. Földiák

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Structural isomerization to open-chain alkenes was observed in the photolysis of methylcyclohexane 1,2-dimethylcyclohexane, 1,3-dimethylcyclohexane and 1,4-dimethylcyclohexane; cis-trans geometrical isomerization was also found in the dimethylcyclohexanes. The results of deuterium labelling experiments on methylcyclohexane and examinations of the product distributions suggest that biradicals are intermediates of both types of isomerization. The lifetime of the biradical state is assumed to be a few times the rotation time around a CC.

Original languageEnglish
Pages (from-to)79-88
Number of pages10
JournalJournal of Photochemistry
Volume19
Issue number1
DOIs
Publication statusPublished - 1982

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