Benzo-1,3,2-diazaphospholide and benzo-1,3,2-diazaphospholium

An isoelectronic aromatic anion-cation pair

Dirk Schmid, Sebastian Loscher, Dietrich Gudat, Denis Bubrin, Ingo Hartenbach, Thomas Schleid, Zoltán Benko, L. Nyulászi

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Isoelectronic benzo-1,3,2-diazaphospholium cations and benzo-1,3,2- diazaphospholide anions were prepared from the same phosphazane precursor; both species display according to computational studies similar aromaticity as the neutral benzo-1,3,2-diazaphosphole but are chemically more stable due to their ionic nature.

Original languageEnglish
Pages (from-to)830-832
Number of pages3
JournalChemical Communications
Issue number7
DOIs
Publication statusPublished - 2009

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Anions
Cations
Negative ions
Positive ions

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Benzo-1,3,2-diazaphospholide and benzo-1,3,2-diazaphospholium : An isoelectronic aromatic anion-cation pair. / Schmid, Dirk; Loscher, Sebastian; Gudat, Dietrich; Bubrin, Denis; Hartenbach, Ingo; Schleid, Thomas; Benko, Zoltán; Nyulászi, L.

In: Chemical Communications, No. 7, 2009, p. 830-832.

Research output: Contribution to journalArticle

Schmid, Dirk ; Loscher, Sebastian ; Gudat, Dietrich ; Bubrin, Denis ; Hartenbach, Ingo ; Schleid, Thomas ; Benko, Zoltán ; Nyulászi, L. / Benzo-1,3,2-diazaphospholide and benzo-1,3,2-diazaphospholium : An isoelectronic aromatic anion-cation pair. In: Chemical Communications. 2009 ; No. 7. pp. 830-832.
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AU - Benko, Zoltán

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