Asymmetric Michael reaction. Deracemization of enolate by chiral crown ether

L. Tőke, László Fenichel, Melinda Albert

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Crown ethers anellated to sugar units have been used to catalyse the enantioselective carbon-carbon bond forming reaction of methyl phenylacetate with methyl acrylate. A novel CH-acid deracemization has also been discovered in this study.

Original languageEnglish
Pages (from-to)5951-5954
Number of pages4
JournalTetrahedron Letters
Volume36
Issue number33
DOIs
Publication statusPublished - Aug 14 1995

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Crown Ethers
Carbon
Sugars
Acids
methyl phenylacetate
methyl acrylate

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Asymmetric Michael reaction. Deracemization of enolate by chiral crown ether. / Tőke, L.; Fenichel, László; Albert, Melinda.

In: Tetrahedron Letters, Vol. 36, No. 33, 14.08.1995, p. 5951-5954.

Research output: Contribution to journalArticle

Tőke, L. ; Fenichel, László ; Albert, Melinda. / Asymmetric Michael reaction. Deracemization of enolate by chiral crown ether. In: Tetrahedron Letters. 1995 ; Vol. 36, No. 33. pp. 5951-5954.
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