Asymmetric induction by amino acid ligands in chromium(II)-assisted reduction of ketones

Julianna Gyarmati, Csongor Hajdu, Z. Dinya, K. Micskei, Claudia Zucchi, Gyula Pályi

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Asymmetric reduction of acetophenone by Cr(II)/amino acid/water/DMF system is reported. Chemical yields up to 94%, enantiomeric excesses up to 74% were observed. The relevance to the Nozaki-Hiyama-Kishi reaction is discussed.

Original languageEnglish
Pages (from-to)106-109
Number of pages4
JournalJournal of Organometallic Chemistry
Volume586
Issue number1
Publication statusPublished - Jul 31 1999

Fingerprint

Chromium
Ketones
ketones
amino acids
Amino acids
chromium
induction
Ligands
Amino Acids
ligands
Water
water
acetophenone

Keywords

  • Asymmetric reduction
  • Chromium
  • Ketones
  • Nozaki-Hiyama-Kishi reaction

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Asymmetric induction by amino acid ligands in chromium(II)-assisted reduction of ketones. / Gyarmati, Julianna; Hajdu, Csongor; Dinya, Z.; Micskei, K.; Zucchi, Claudia; Pályi, Gyula.

In: Journal of Organometallic Chemistry, Vol. 586, No. 1, 31.07.1999, p. 106-109.

Research output: Contribution to journalArticle

Gyarmati, Julianna ; Hajdu, Csongor ; Dinya, Z. ; Micskei, K. ; Zucchi, Claudia ; Pályi, Gyula. / Asymmetric induction by amino acid ligands in chromium(II)-assisted reduction of ketones. In: Journal of Organometallic Chemistry. 1999 ; Vol. 586, No. 1. pp. 106-109.
@article{ff380af8439d459fa1a5ca06a18a2565,
title = "Asymmetric induction by amino acid ligands in chromium(II)-assisted reduction of ketones",
abstract = "Asymmetric reduction of acetophenone by Cr(II)/amino acid/water/DMF system is reported. Chemical yields up to 94{\%}, enantiomeric excesses up to 74{\%} were observed. The relevance to the Nozaki-Hiyama-Kishi reaction is discussed.",
keywords = "Asymmetric reduction, Chromium, Ketones, Nozaki-Hiyama-Kishi reaction",
author = "Julianna Gyarmati and Csongor Hajdu and Z. Dinya and K. Micskei and Claudia Zucchi and Gyula P{\'a}lyi",
year = "1999",
month = "7",
day = "31",
language = "English",
volume = "586",
pages = "106--109",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",
number = "1",

}

TY - JOUR

T1 - Asymmetric induction by amino acid ligands in chromium(II)-assisted reduction of ketones

AU - Gyarmati, Julianna

AU - Hajdu, Csongor

AU - Dinya, Z.

AU - Micskei, K.

AU - Zucchi, Claudia

AU - Pályi, Gyula

PY - 1999/7/31

Y1 - 1999/7/31

N2 - Asymmetric reduction of acetophenone by Cr(II)/amino acid/water/DMF system is reported. Chemical yields up to 94%, enantiomeric excesses up to 74% were observed. The relevance to the Nozaki-Hiyama-Kishi reaction is discussed.

AB - Asymmetric reduction of acetophenone by Cr(II)/amino acid/water/DMF system is reported. Chemical yields up to 94%, enantiomeric excesses up to 74% were observed. The relevance to the Nozaki-Hiyama-Kishi reaction is discussed.

KW - Asymmetric reduction

KW - Chromium

KW - Ketones

KW - Nozaki-Hiyama-Kishi reaction

UR - http://www.scopus.com/inward/record.url?scp=0000853998&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000853998&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0000853998

VL - 586

SP - 106

EP - 109

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 1

ER -