Article improved optical and morphological properties of vinyl-substituted hybrid silica materials incorporating a Zn-metalloporphyrin

Zoltán Dudás, Eugenia Fagadar-Cosma, Adél Len, Loránd Románszki, L. Almásy, Beatrice Vlad-Oros, Daniela Dascalu, Andraž Krajnc, Manfred Kriechbaum, Andrei Kuncser

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

This work is focused on a novel class of hybrid materials exhibiting enhanced optical properties and high surface areas that combine the morphology offered by the vinyl substituted silica host, and the excellent absorption and emission properties of 5,10,15,20-tetrakis(N-methyl-4- pyridyl)porphyrin-Zn(II) tetrachloride as a water soluble guest molecule. In order to optimize the synthesis procedure and the performance of the immobilized porphyrin, silica precursor mixtures of different compositions were used. To achieve the requirements regarding the hydrophobicity and the porous structure of the gels for the successful incorporation of porphyrin, the content of vinyltriacetoxysilane was systematically changed and thoroughly investigated. Substitution of the silica gels with organic groups is a viable way to provide new properties to the support. An exhaustive characterization of the synthesized silica samples was realised by complementary physicochemical methods, such as infrared spectroscopy (FT-IR), absorption spectroscopy (UV-Vis) and photoluminescence, nuclear magnetic resonance spectroscopy (29Si-MAS-NMR) transmission and scanning electron microscopy (TEM and SEM), nitrogen absorption (BET), contact angle (CA), small angle X ray and neutron scattering (SAXS and SANS). All hybrids showed an increase in emission intensity in the wide region from 575 to 725 nm (Q bands) in comparison with bare porphyrin. By simply tuning the vinyltriacetoxysilane content, the hydrophilic/hydrophobic profile of the hybrid materials was changed, while maintaining a high surface area. Good control of hydrophobicity is important to enhance properties such as dispersion, stability behaviour, and resistance to water, in order to achieve highly dispersible systems in water for biomedical applications.

Original languageEnglish
Article number565
JournalMaterials
Volume11
Issue number4
DOIs
Publication statusPublished - Apr 6 2018

Fingerprint

Metalloporphyrins
Porphyrins
Silicon Dioxide
Silica
Hybrid materials
Hydrophobicity
Water
Transmission electron microscopy
Scanning electron microscopy
Silica Gel
Silica gel
Neutron scattering
X ray scattering
Absorption spectroscopy
Nuclear magnetic resonance spectroscopy
Contact angle
Infrared spectroscopy
Photoluminescence
Substitution reactions
Nitrogen

Keywords

  • Hybrid silica materials
  • Optical properties
  • Physicochemical characterization
  • Porphyrin
  • Sol-gel technique
  • Vinyltriacetoxysilane

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Article improved optical and morphological properties of vinyl-substituted hybrid silica materials incorporating a Zn-metalloporphyrin. / Dudás, Zoltán; Fagadar-Cosma, Eugenia; Len, Adél; Románszki, Loránd; Almásy, L.; Vlad-Oros, Beatrice; Dascalu, Daniela; Krajnc, Andraž; Kriechbaum, Manfred; Kuncser, Andrei.

In: Materials, Vol. 11, No. 4, 565, 06.04.2018.

Research output: Contribution to journalArticle

Dudás, Z, Fagadar-Cosma, E, Len, A, Románszki, L, Almásy, L, Vlad-Oros, B, Dascalu, D, Krajnc, A, Kriechbaum, M & Kuncser, A 2018, 'Article improved optical and morphological properties of vinyl-substituted hybrid silica materials incorporating a Zn-metalloporphyrin', Materials, vol. 11, no. 4, 565. https://doi.org/10.3390/ma11040565
Dudás, Zoltán ; Fagadar-Cosma, Eugenia ; Len, Adél ; Románszki, Loránd ; Almásy, L. ; Vlad-Oros, Beatrice ; Dascalu, Daniela ; Krajnc, Andraž ; Kriechbaum, Manfred ; Kuncser, Andrei. / Article improved optical and morphological properties of vinyl-substituted hybrid silica materials incorporating a Zn-metalloporphyrin. In: Materials. 2018 ; Vol. 11, No. 4.
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