Arsenic-rich Cu-Ni-PGE mineralization in Wetlegs, Duluth complex, St. Louis county, Minnesota, USA

Sara Raič, Aberra Mogessie, Zsolt Benkó, F. Molnár, Steven Hauck, Mark Severson

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The magmatic Cu-Ni ± PGE (platinum group elements) sulfide deposit Wetlegs within the troctolitic Partridge River intrusion (PRI) of the 1.1 Ga Duluth Complex (northeastern Minnesota) contains disseminated low-grade Cu-Ni sulfide minerals distributed along its heterogeneous base. The main association consists of magmatic intercumulus pyrrhotite, chalco-pyrite, pentlandite, and cubanite. Secondary copper-bearing sulfide minerals (bornite, covellite, yarrowite, and digenite) are found within variously altered troctolites. Several late stage arsenic-rich phases occur in altered troctolitic rocks and underlying metasedimentary footwall hosts (Virginia Formation). They appear as nickeline, maucherite, and diarsenides in the system rammelsbergite-safflorite-loellingite, and sulfarsenides of the cobaltite-gersdorffite solid-solution series. Based on their textural relationships and chemistries a three stage depositional history is suggested, starting with the formation of nickeline, followed by diarsenides enriched in Co (below 600 °C) and the late Co-rich sulfarsenides (between 550 °C and 400 °C) in the troctolitic host rock. Due to the higher Ni- and Fe-contents, higher formation temperatures are proposed for arsenides (below 625 °C) and sulfarsenides (∼600 °C) in the recrystallized microveins of the footwall. The restricted appearance in altered troctolitic rocks and underlying recrystallized footwall metasediments (Virginia Formation) suggest a deposition of arsenic-rich phases by late-stage hydrothermal fluids. In addition, the metasedimentary Virginia Formation may be a potential source of elements necessary to form arsenides and sulfarsenides, which is further supported by elevated 5 S values (7gt;9%o) for samples from the arsenide assemblages. The platinum-group minerals (PGMs; sperrylite, stibiopalladinite) and precious element-bearing phases are either associated with primary magmatic sulfides, or hydrothermally altered silicate patches (amphibole, chlorite, sericite, prehnite, carbonates, and serpentine). These associations suggest two sources for PGMs: fractionation of a sulfide-saturated melt, and a remobilization and re-deposition of platinum-group elements (PGEs) in the form of aqueous complexes during the late-stage hydrothermal events.

Original languageEnglish
Pages (from-to)105-132
Number of pages28
JournalCanadian Mineralogist
Volume53
Issue number1
DOIs
Publication statusPublished - Jan 1 2015

Fingerprint

platinum group element
Arsenic
Sulfides
Bearings (structural)
Platinum
Sulfide minerals
arsenic
Rocks
sulfide
mineralization
footwall
Amphibole Asbestos
Silicates
Carbonates
Fractionation
mineral
Minerals
cobaltite
Copper
Solid solutions

Keywords

  • Arsenides
  • Hydrothermal alteration
  • Platinum-group minerals
  • Sulfarsenides
  • Wetlegs

ASJC Scopus subject areas

  • Geochemistry and Petrology

Cite this

Arsenic-rich Cu-Ni-PGE mineralization in Wetlegs, Duluth complex, St. Louis county, Minnesota, USA. / Raič, Sara; Mogessie, Aberra; Benkó, Zsolt; Molnár, F.; Hauck, Steven; Severson, Mark.

In: Canadian Mineralogist, Vol. 53, No. 1, 01.01.2015, p. 105-132.

Research output: Contribution to journalArticle

Raič, Sara ; Mogessie, Aberra ; Benkó, Zsolt ; Molnár, F. ; Hauck, Steven ; Severson, Mark. / Arsenic-rich Cu-Ni-PGE mineralization in Wetlegs, Duluth complex, St. Louis county, Minnesota, USA. In: Canadian Mineralogist. 2015 ; Vol. 53, No. 1. pp. 105-132.
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