Anomalous wittig reaction of aldonic thioamide derivatives. A new mode of thiazole ring formation

László Somogyi, Pál Herczegh, Gyula Batta

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

A new mode of thiazole ring formation and an unexpected acetoxy group elimination were observed as a result of the reaction of N-acetyl-per-O-acetylhexonic thioamides (lb and 2b) with ethoxy-carbonylmethylenetriphenylphosphorane affording ethyl 2-(1′,5′-diacetoxy-penta-1′,3′-Z,E-dien-1′-yl)-4-methylthiazole-5-carboxylate (6).

Original languageEnglish
Pages (from-to)2735-2738
Number of pages4
JournalHeterocycles
Volume24
Issue number10
DOIs
Publication statusPublished - Oct 1 1986

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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