An "in situ" reaction of propagating chain-end as iodoacetal in the polymerization of butyl vinyl ether initiated by I2 and HI/I2 systems

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Abstract

The polymerization reaction of butyl vinyl ether with initiating systems I2 and HI/I2 was investigated with glass fiber photometry and conductometry by monitoring the characteristic changes in the absorbance versus time curve and in the conductivity versus time curve. Aldehyde end-groups were observed and a mechanism of their formation is proposed.

Original languageEnglish
Pages (from-to)3599-3604
Number of pages6
JournalMacromolecular Chemistry and Physics
Volume198
Issue number11
DOIs
Publication statusPublished - Nov 1997

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ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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