An aromatic-antiaromatic switch in P-heteroles. A small change in delocalisation makes a big reactivity difference

L. Nyulászi, Oldamur Hollóczki, Christophe Lescop, Muriel Hissler, Régis Réau

Research output: Contribution to journalArticle

48 Citations (Scopus)

Abstract

The low aromaticity of phosphole can be switched to low antiaromaticity by oxidizing the phosphorus atom. This subtle change in the mode of delocalisation alters substantially the chemical behaviour of these heteroles.

Original languageEnglish
Pages (from-to)996-998
Number of pages3
JournalOrganic and Biomolecular Chemistry
Volume4
Issue number6
DOIs
Publication statusPublished - 2006

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Phosphorus
phosphorus
switches
reactivity
Switches
Atoms
atoms

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)
  • Chemistry(all)

Cite this

An aromatic-antiaromatic switch in P-heteroles. A small change in delocalisation makes a big reactivity difference. / Nyulászi, L.; Hollóczki, Oldamur; Lescop, Christophe; Hissler, Muriel; Réau, Régis.

In: Organic and Biomolecular Chemistry, Vol. 4, No. 6, 2006, p. 996-998.

Research output: Contribution to journalArticle

Nyulászi, L. ; Hollóczki, Oldamur ; Lescop, Christophe ; Hissler, Muriel ; Réau, Régis. / An aromatic-antiaromatic switch in P-heteroles. A small change in delocalisation makes a big reactivity difference. In: Organic and Biomolecular Chemistry. 2006 ; Vol. 4, No. 6. pp. 996-998.
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