An aromatic-antiaromatic switch in P-heteroles. A small change in delocalisation makes a big reactivity difference

László Nyulászi, Oldamur Hollóczki, Christophe Lescop, Muriel Hissler, Régis Réau

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

The low aromaticity of phosphole can be switched to low antiaromaticity by oxidizing the phosphorus atom. This subtle change in the mode of delocalisation alters substantially the chemical behaviour of these heteroles.

Original languageEnglish
Pages (from-to)996-998
Number of pages3
JournalOrganic and Biomolecular Chemistry
Volume4
Issue number6
DOIs
Publication statusPublished - Mar 20 2006

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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