Aminocarbonylation of 1,1′-diiodoferrocene, two-step synthesis of heterodisubstituted ferrocene derivatives via homogeneous catalytic carbonylation/coupling reactions

Zsolt Szarka, Árpád Kuik, Rita Skoda-Földes, László Kollár

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Detailed investigation of the catalytic carbonylation of 1,1′-diiodoferrocene has been carried out. The importance of the 1′-iodo-ferrocenecarboxamide- or 1′-iodo-ferroceneglyoxylic amide-type products as starting materials for the synthesis of various heterodisubstituted ferrocenes, that can serve as starting materials for ferrocene-based biosensors, was also proved. The potential of this reaction sequence was shown by the high-yielding synthesis of 1′-vinyl ferrocenecarboxamide/glyoxylic amide and 1′-acyl ferrocencarboxamide derivatives.

Original languageEnglish
Pages (from-to)2770-2775
Number of pages6
JournalJournal of Organometallic Chemistry
Volume689
Issue number17
DOIs
Publication statusPublished - Sep 1 2004

Keywords

  • Carbonylation
  • Disubstituted ferrocenes
  • Ferrocene amides
  • Homogeneous catalysis
  • Pd-catalysts

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Aminocarbonylation of 1,1′-diiodoferrocene, two-step synthesis of heterodisubstituted ferrocene derivatives via homogeneous catalytic carbonylation/coupling reactions'. Together they form a unique fingerprint.

  • Cite this