Alkylcobalt carbonyls. 9. Alkoxy-, silyloxy-, and hydroxy-substituted methyl- and acetylcobalt carbonyls. Reduction of formaldehyde to methanol by hydridocobalt tetracarbonyl

Attila Sisak, Ella Sámpár-Szerencsés, Vilmos Galamb, László Németh, Ferenc Ungváry, Gyula Pályi

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

(Alkoxymethyl)-, ((silyloxy)methyl)-, and (hydroxymethyl)cobalt and (alkoxyacetyl)-, ((silyloxy)acetyl)-, and (hydroxyacetyl)cobalt tetracarbonyls and phosphine-substituted derivatives were prepared. The interconversions of these compounds by carbonylation/decarbonylation, methylation, and silylation were explored. In situ prepared hydroxymethylcobalt tetracarbonyl reacts with excess HCo(CO)4 to methanol and Co2(CO)8 under mild conditions.

Original languageEnglish
Pages (from-to)1096-1100
Number of pages5
JournalOrganometallics
Volume8
Issue number4
Publication statusPublished - 1989

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phosphine
Cobalt
formaldehyde
Formaldehyde
Methanol
cobalt
methyl alcohol
Carbonylation
methylation
Methylation
phosphines
Derivatives
alkoxyl radical

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Alkylcobalt carbonyls. 9. Alkoxy-, silyloxy-, and hydroxy-substituted methyl- and acetylcobalt carbonyls. Reduction of formaldehyde to methanol by hydridocobalt tetracarbonyl. / Sisak, Attila; Sámpár-Szerencsés, Ella; Galamb, Vilmos; Németh, László; Ungváry, Ferenc; Pályi, Gyula.

In: Organometallics, Vol. 8, No. 4, 1989, p. 1096-1100.

Research output: Contribution to journalArticle

Sisak, Attila ; Sámpár-Szerencsés, Ella ; Galamb, Vilmos ; Németh, László ; Ungváry, Ferenc ; Pályi, Gyula. / Alkylcobalt carbonyls. 9. Alkoxy-, silyloxy-, and hydroxy-substituted methyl- and acetylcobalt carbonyls. Reduction of formaldehyde to methanol by hydridocobalt tetracarbonyl. In: Organometallics. 1989 ; Vol. 8, No. 4. pp. 1096-1100.
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AU - Sámpár-Szerencsés, Ella

AU - Galamb, Vilmos

AU - Németh, László

AU - Ungváry, Ferenc

AU - Pályi, Gyula

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