Aerobic oxidations on metal macrocycles encapsulated in zeolites

A. Zsigmond, F. Notheisz, Zs Szegletes, J. E. Bäckvall

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Zeolite-encapsulated Fe-phthalocyanine and Co-salophen catalysts were used in the palladium-catalyzed aerobic oxidation of hydroquinone to benzoquinone, in the oxidation of l-octene to 2-octanone and in the allylic oxidation of cyclohexene to 3-acetoxycyclohexene. These catalysts proved to be active in the above reactions and they were stable towards self-oxidation and it was possible to reuse them in subsequent runs. The specific activity of the encapsulated Fe-phthalocyanine catalyst was about four times higher than those of the free complex.

Original languageEnglish
Pages (from-to)728-735
Number of pages8
JournalStudies in Surface Science and Catalysis
Volume94
Issue numberC
DOIs
Publication statusPublished - 1995

Fingerprint

Zeolites
zeolites
Metals
Oxidation
oxidation
catalysts
metals
Catalysts
reuse
Palladium
quinones
palladium
phthalocyanine

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Catalysis
  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Surfaces, Coatings and Films

Cite this

Aerobic oxidations on metal macrocycles encapsulated in zeolites. / Zsigmond, A.; Notheisz, F.; Szegletes, Zs; Bäckvall, J. E.

In: Studies in Surface Science and Catalysis, Vol. 94, No. C, 1995, p. 728-735.

Research output: Contribution to journalArticle

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