Aerobic oxidation of oct-1-ene in a nanoscale microreactor

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Abstract

Nanoscale microreactors containing the Pd(II)/Pd(0)-1,4-benzoquinone/hydroquinone-CoSalophen OX/ CoSalophen triple catalytic system were constructed in the supercages of zeolite Y. This catalytic system works as a closed reactor and is capable for the highly selective palladium-catalyzed oxidation of oct-1-ene to octan-2-one with molecular oxygen at room temperature.

Original languageEnglish
Pages (from-to)225-232
Number of pages8
JournalReaction Kinetics and Catalysis Letters
Volume74
Issue number2
DOIs
Publication statusPublished - Dec 1 2001

Keywords

  • Aerobic oxidation
  • Encapsulated catalysts
  • Pd-catalyzed oxidation
  • Zeolite Y

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

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