Adsorption of Cl- ions on electrodeposited rhodium black layer (rhodized electrode) at low concentrations

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Abstract

The adsorption of Cl- ions on rhodhim black layer (rhodized electrodes) was studied by radiotracer technique at low Cl- ion concentrations (c ≪ 10-5 mol dm-3) in 1 mol dm-3 H2SO4 supporting electrolyte. The specific adsorption of Cl- ions was treated in terms of partition between solution phase and electrodeposited Rh black layer. The potential dependence of the partition coefficient is determined.

Original languageEnglish
Pages (from-to)211-217
Number of pages7
JournalReaction Kinetics and Catalysis Letters
Volume59
Issue number2
DOIs
Publication statusPublished - Jan 1 1996

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Keywords

  • Cl ions
  • Partition
  • Radiotracer technique
  • Rhodium
  • Specific adsorption

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

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