Abstract
Adducts of four phosphine chalcogenides with the chiral dirhodium complex ([Rh-Rh]) were investigated by variable-temperature 1H and 31P NMR spectroscopy in order to compare their properties as axial ligands. Whereas the selenide (1) and the sulfide (2) are strong ligands with electrostatic attration and, in addition, a significant orbital (HOMO-LUMO) interaction, the phosphine oxide compounds (P=O) bind primarily via electrostatic attraction and are relatively weak donors. Moreover, the overall bond strength in these adducts depends on steric congestion around the P=O group.
| Original language | English |
|---|---|
| Pages (from-to) | 600-604 |
| Number of pages | 5 |
| Journal | Magnetic Resonance in Chemistry |
| Volume | 42 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - Jul 2004 |
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Keywords
- H NMR
- P NMR
- Se NMR
- Adduct formation
- Dirhodium complexes
- NMR
- Phosphine chalcogenides
- Variable-temperature NMR
ASJC Scopus subject areas
- Chemistry(all)
- Physical and Theoretical Chemistry
- Spectroscopy
Cite this
Adducts of Rh2[MTPA]4 with some phosphine chalcogenides : Nature of binding and ligand exchange. / Gáti, Tamás; Simon, A.; Tóth, Gábor; Magiera, Damian; Moeller, Stefan; Duddeck, Helmut.
In: Magnetic Resonance in Chemistry, Vol. 42, No. 7, 07.2004, p. 600-604.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Adducts of Rh2[MTPA]4 with some phosphine chalcogenides
T2 - Nature of binding and ligand exchange
AU - Gáti, Tamás
AU - Simon, A.
AU - Tóth, Gábor
AU - Magiera, Damian
AU - Moeller, Stefan
AU - Duddeck, Helmut
PY - 2004/7
Y1 - 2004/7
N2 - Adducts of four phosphine chalcogenides with the chiral dirhodium complex ([Rh-Rh]) were investigated by variable-temperature 1H and 31P NMR spectroscopy in order to compare their properties as axial ligands. Whereas the selenide (1) and the sulfide (2) are strong ligands with electrostatic attration and, in addition, a significant orbital (HOMO-LUMO) interaction, the phosphine oxide compounds (P=O) bind primarily via electrostatic attraction and are relatively weak donors. Moreover, the overall bond strength in these adducts depends on steric congestion around the P=O group.
AB - Adducts of four phosphine chalcogenides with the chiral dirhodium complex ([Rh-Rh]) were investigated by variable-temperature 1H and 31P NMR spectroscopy in order to compare their properties as axial ligands. Whereas the selenide (1) and the sulfide (2) are strong ligands with electrostatic attration and, in addition, a significant orbital (HOMO-LUMO) interaction, the phosphine oxide compounds (P=O) bind primarily via electrostatic attraction and are relatively weak donors. Moreover, the overall bond strength in these adducts depends on steric congestion around the P=O group.
KW - H NMR
KW - P NMR
KW - Se NMR
KW - Adduct formation
KW - Dirhodium complexes
KW - NMR
KW - Phosphine chalcogenides
KW - Variable-temperature NMR
UR - http://www.scopus.com/inward/record.url?scp=8144223873&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=8144223873&partnerID=8YFLogxK
U2 - 10.1002/mrc.1388
DO - 10.1002/mrc.1388
M3 - Article
C2 - 15181630
AN - SCOPUS:8144223873
VL - 42
SP - 600
EP - 604
JO - Magnetic Resonance in Chemistry
JF - Magnetic Resonance in Chemistry
SN - 0749-1581
IS - 7
ER -