Activation of C-H Activation: The Beneficial Effect of Catalytic Amount of Triaryl Boranes on Palladium-Catalyzed C-H Activation

Orsolya Tischler, Zsófia Bokányi, Z. Novák

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Herein we report a novel approach to the acceleration of palladium-catalyzed C-H activation reactions. We demonstrated that the utilization of electron-deficient triaryl boranes as Lewis acidic cocatalysts of palladium enables the directed cross dehydrogenative coupling of aldehydes and anilides under mild reaction conditions. Study of the kinetic profile of the transformation reveals a unique, unexpectedly long induction period of the transformation.

Original languageEnglish
Pages (from-to)741-746
Number of pages6
JournalOrganometallics
Volume35
Issue number5
DOIs
Publication statusPublished - Mar 14 2016

Fingerprint

Boranes
boranes
Palladium
palladium
Anilides
Chemical activation
activation
cross coupling
aldehydes
Aldehydes
induction
Kinetics
Electrons
kinetics
profiles
electrons

ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Activation of C-H Activation : The Beneficial Effect of Catalytic Amount of Triaryl Boranes on Palladium-Catalyzed C-H Activation. / Tischler, Orsolya; Bokányi, Zsófia; Novák, Z.

In: Organometallics, Vol. 35, No. 5, 14.03.2016, p. 741-746.

Research output: Contribution to journalArticle

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