Acetone improves the topographical homogeneity of liquid phase exfoliated few-layer black phosphorus flakes

Juan Gómez-Pérez, Z. Kónya, Á. Kukovecz

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Liquid phase exfoliation of 2D materials has issues related to the sorption of the solvent, the oxidation of the sample during storage, and the topographical inhomogeneity of the exfoliated material. N-methyl-2-pyrrolidone (NMP), a common solvent for black phosphorus (BP) exfoliation, has additional drawbacks like the formation of by-products during sonication and poor solvent volatility. Here we demonstrate an improvement in the topographical homogeneity (i.e. thickness and lateral dimensions) of NMP-exfoliated BP flakes after resuspension in acetone. The typical size of monolayers and bilayers stabilised in acetone was 99.8±27.4 nm and 159.1±57 nm, respectively. These standard deviations represent a threefold improvement over those of the NMPexfoliated originals. Phosphorene can also be exfoliated directly in acetone by very long ultrasonication. The product suspension enjoys the same dimensional homogeneity benefits, which confirms that this effect is an intrinsic property of the acetoneBP system. The quality and stability of the exfoliated flakes was checked by XRD, TEM, electron diffraction and Raman spectroscopy. Thermal expansion coefficients of the Ag, 1 B2gand Ag 2 Raman modes were calculated for dropcasted samples as -0.018 28 cm-1 K1, -0.030 56 cm-1 K1 and -0.032 19 cm-1 K1, respectively. The flakes withstand 20min in O2 flow at 373 K without lattice distortion.

Original languageEnglish
Article number365303
JournalNanotechnology
Volume29
Issue number36
DOIs
Publication statusPublished - Jun 29 2018

Keywords

  • exfoliated black phosphorus
  • lattice parameters
  • liquid phase exfoliation
  • phosphorene
  • solvent exchange
  • thermal expansion coefficient

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering
  • Electrical and Electronic Engineering

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