Absolute configuration of 1β,10β-epoxydesacetoxymatricarin isolated from Carthamus oxycantha by means of TDDFT CD calculations

Zahid Hassan, Hidayat Hussain, Viqar Uddin Ahmad, Shazia Anjum, Gennaro Pescitelli, Tibor Kurtán, Karsten Krohn

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

The absolute configuration of 1β,10β-epoxydesacetoxymatricarin 1, a sesquiterpenoid isolated from Carthamus oxycantha, was established by TDDFT CD calculations in combination with single crystal X-ray analysis. Since the solid-state CD spectrum shows contributions from intermolecular interactions in the crystal, 1 represents a test case for our solid-state CD/TDDFT approach.

Original languageEnglish
Pages (from-to)2905-2909
Number of pages5
JournalTetrahedron Asymmetry
Volume18
Issue number24
DOIs
Publication statusPublished - Dec 10 2007

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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