Ab initio molecular orbital calculations on H2NPH2. The stereochemistry at nitrogen

I. Csizmadia, A. H. Cowley, M. W. Taylor, Luis M. Tel, Saul Wolfe

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

Ab initio SCF-MO calculations on amino-phosphine, H2NPH 2, indicate that the nitrogen atom adopts a trigonal planar geometry, as a consequence of inductive electron release from the PH2 group.

Original languageEnglish
Pages (from-to)1147-1148
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Volume0
Issue number20
DOIs
Publication statusPublished - 1972

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phosphine
Orbital calculations
Stereochemistry
Molecular orbitals
Nitrogen
Electrons
Atoms
Geometry

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Ab initio molecular orbital calculations on H2NPH2. The stereochemistry at nitrogen. / Csizmadia, I.; Cowley, A. H.; Taylor, M. W.; Tel, Luis M.; Wolfe, Saul.

In: Journal of the Chemical Society, Chemical Communications, Vol. 0, No. 20, 1972, p. 1147-1148.

Research output: Contribution to journalArticle

Csizmadia, I. ; Cowley, A. H. ; Taylor, M. W. ; Tel, Luis M. ; Wolfe, Saul. / Ab initio molecular orbital calculations on H2NPH2. The stereochemistry at nitrogen. In: Journal of the Chemical Society, Chemical Communications. 1972 ; Vol. 0, No. 20. pp. 1147-1148.
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