Barriers to pyramidal inversion of directly bonded three-co-ordinate atoms exhibit an interdependence which is determined principally by the differences in the electronegativities of these atoms; thus the phosphorus inversion barrier in H2NPH2 is higher than that in PH3.
|Number of pages||2|
|Journal||Journal of the Chemical Society, Chemical Communications|
|Publication status||Published - Jan 1 1974|
ASJC Scopus subject areas
- Molecular Medicine