A trifluoromethyl group directed semipinacol rearrangement

Synthesis of α-(trifluoroacetyl) diarylmethanes

Gyula Hornyák, J. Fetter, G. ábor Németh, L. Poszávácz, Gyula Simig

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Semipinacol rearrangements of trifluoromethyl substituted vic-diol monomethyl ethers proceeded smoothly to give α-(trifluoroacetyl) diarylmethanes in good yields. The trifluoromethyl group gave specific orientation to the course of the rearrangement.

Original languageEnglish
Pages (from-to)49-51
Number of pages3
JournalJournal of Fluorine Chemistry
Volume84
Issue number1
Publication statusPublished - Aug 31 1997

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Keywords

  • α-(trifluoroacetyl) diarylmethanes
  • Pinacol rearrangement
  • Semipinacol rearrangement

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Materials Chemistry
  • Polymers and Plastics

Cite this

A trifluoromethyl group directed semipinacol rearrangement : Synthesis of α-(trifluoroacetyl) diarylmethanes. / Hornyák, Gyula; Fetter, J.; Németh, G. ábor; Poszávácz, L.; Simig, Gyula.

In: Journal of Fluorine Chemistry, Vol. 84, No. 1, 31.08.1997, p. 49-51.

Research output: Contribution to journalArticle

Hornyák, Gyula ; Fetter, J. ; Németh, G. ábor ; Poszávácz, L. ; Simig, Gyula. / A trifluoromethyl group directed semipinacol rearrangement : Synthesis of α-(trifluoroacetyl) diarylmethanes. In: Journal of Fluorine Chemistry. 1997 ; Vol. 84, No. 1. pp. 49-51.
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