A thermally induced low-temperature intramolecular redox reaction of bis(pyridine)silver(I) permanganate and its hemipyridine solvate

László Kótai, Judit Fodor, Emma Jakab, István Sajó, Piroska Szabó, Ferenc Lónyi, József Valyon, István Gács, Gyula Argay, Kalyan K. Banerji

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Among the known three pyridine complexes of silver permanganate, i.e. [Agpy2]MnO4 (1), [Agpy2.25]MnO4 or 7[Agpy2]MnO4[Agpy4]MnO4 (2) and [Agpy2]MnO40.5py (3), compounds (1) and (2) were studied by means of thermal analysis and TG-MS methods. Presuming identical structural motifs for the Agpy2MnO4 blocks in (1) as it has been found in its solvate (3) by single-crystal diffraction, α-C-H...O-Mn H-bonded structures are responsible for a thermally induced low-temperature intramolecular redox reaction observed for the first time between the [Agpy 2]+ cation and permanganate anion.

Original languageEnglish
Pages (from-to)30-34
Number of pages5
JournalTransition Metal Chemistry
Volume31
Issue number1
DOIs
Publication statusPublished - Feb 1 2006

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Metals and Alloys
  • Materials Chemistry

Fingerprint Dive into the research topics of 'A thermally induced low-temperature intramolecular redox reaction of bis(pyridine)silver(I) permanganate and its hemipyridine solvate'. Together they form a unique fingerprint.

  • Cite this