A 1H NMR study of the tropylium ion, partially oriented in a lyotropic solvent

P. Diehl, J. Jokisaari, G. Dombi

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Abstract

The 1H NMR spectrum of tropylium fluoroborate dissolved and oriented in a lyotropic decyl sulphate phase has been recorded and analysed. Direct as well as indirect HH coupling constants have been obtained. The vibrationally uncorrected proton skeleton structure deviates slightly from a regular heptagon. The deviations are between two and three times larger than those of benzene from a hexagon, previously observed in the same solvent.

Original languageEnglish
Pages (from-to)438-439
Number of pages2
JournalMagnetic Resonance in Chemistry
Volume12
Issue number7
DOIs
Publication statusPublished - 1979

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ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)

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