A study on the deoxygenation of phosphine oxides by different silane derivatives

Tamara Kovács, Anita Urbanics, Flóra Csatlós, Judith Binder, Astrid Falk, Frank Uhlig, G. Keglevich

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The deoxygenation of phosphine oxides was studied on two model reactions, on the reduction of 3-methyl-1-phenyl-3-phospholene 1-oxide and triphenylphosphine oxide using an aralkylsilane, arylsilanes, diarylsilanes, a disiloxane, a polysiloxane and a disilane under solvent-free, thermal or microwave-assisted conditions. The deoxygenations were optimized, and the reactivity of the silanes was evaluated. User-friendly accomplishments were elaborated.

Original languageEnglish
Pages (from-to)148-153
Number of pages6
JournalCurrent Organic Synthesis
Volume13
Issue number1
Publication statusPublished - 2016

Fingerprint

phosphine
Siloxanes
Silanes
Oxides
Microwaves
Derivatives
Hot Temperature
triphenylphosphine oxide
disiloxane

Keywords

  • Deoxygenation
  • Microwave
  • Phosphine oxides
  • Phosphines
  • Silanes
  • User friendly reagents

ASJC Scopus subject areas

  • Organic Chemistry
  • Biochemistry

Cite this

Kovács, T., Urbanics, A., Csatlós, F., Binder, J., Falk, A., Uhlig, F., & Keglevich, G. (2016). A study on the deoxygenation of phosphine oxides by different silane derivatives. Current Organic Synthesis, 13(1), 148-153.

A study on the deoxygenation of phosphine oxides by different silane derivatives. / Kovács, Tamara; Urbanics, Anita; Csatlós, Flóra; Binder, Judith; Falk, Astrid; Uhlig, Frank; Keglevich, G.

In: Current Organic Synthesis, Vol. 13, No. 1, 2016, p. 148-153.

Research output: Contribution to journalArticle

Kovács, T, Urbanics, A, Csatlós, F, Binder, J, Falk, A, Uhlig, F & Keglevich, G 2016, 'A study on the deoxygenation of phosphine oxides by different silane derivatives', Current Organic Synthesis, vol. 13, no. 1, pp. 148-153.
Kovács T, Urbanics A, Csatlós F, Binder J, Falk A, Uhlig F et al. A study on the deoxygenation of phosphine oxides by different silane derivatives. Current Organic Synthesis. 2016;13(1):148-153.
Kovács, Tamara ; Urbanics, Anita ; Csatlós, Flóra ; Binder, Judith ; Falk, Astrid ; Uhlig, Frank ; Keglevich, G. / A study on the deoxygenation of phosphine oxides by different silane derivatives. In: Current Organic Synthesis. 2016 ; Vol. 13, No. 1. pp. 148-153.
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