A study of the selective catalytic hydroconversion of biomass-derived pyrolysis or fermentation liquids using propylamine and acetic acid as model reactants

A. C. Badari, Sz Harnos, F. Lónyi, G. Onyestyák, M. Štolcová, A. Kaszonyi, J. Valyon

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Silica-supported P or In modified Ni catalysts were active in the hydrodenitrogenation (HDN) and hydrodeoxygenation (HDO) of reactant propylamine (PA) and acetic acid (AA), respectively, in which reactants were selected to model platform molecules of biomass origin. The undesired CC hydrogenolysis activity of supported Ni catalyst, resulting in low value gaseous products, could be reined by the modification, generating silica-supported Ni2P and Ni2In active phases.

Original languageEnglish
Pages (from-to)1-5
Number of pages5
JournalCatalysis Communications
Volume58
DOIs
Publication statusPublished - Aug 19 2014

Fingerprint

Propylamines
Acetic acid
Silicon Dioxide
Acetic Acid
Fermentation
Biomass
Pyrolysis
Silica
Hydrogenolysis
Catalysts
Liquids
Molecules

Keywords

  • Acetic acid
  • Bio-oil conversion
  • HDN
  • HDO
  • NiIn/SiO
  • NiP/SiO
  • Propylamine

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology
  • Chemistry(all)

Cite this

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abstract = "Silica-supported P or In modified Ni catalysts were active in the hydrodenitrogenation (HDN) and hydrodeoxygenation (HDO) of reactant propylamine (PA) and acetic acid (AA), respectively, in which reactants were selected to model platform molecules of biomass origin. The undesired CC hydrogenolysis activity of supported Ni catalyst, resulting in low value gaseous products, could be reined by the modification, generating silica-supported Ni2P and Ni2In active phases.",
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AU - Badari, A. C.

AU - Harnos, Sz

AU - Lónyi, F.

AU - Onyestyák, G.

AU - Štolcová, M.

AU - Kaszonyi, A.

AU - Valyon, J.

PY - 2014/8/19

Y1 - 2014/8/19

N2 - Silica-supported P or In modified Ni catalysts were active in the hydrodenitrogenation (HDN) and hydrodeoxygenation (HDO) of reactant propylamine (PA) and acetic acid (AA), respectively, in which reactants were selected to model platform molecules of biomass origin. The undesired CC hydrogenolysis activity of supported Ni catalyst, resulting in low value gaseous products, could be reined by the modification, generating silica-supported Ni2P and Ni2In active phases.

AB - Silica-supported P or In modified Ni catalysts were active in the hydrodenitrogenation (HDN) and hydrodeoxygenation (HDO) of reactant propylamine (PA) and acetic acid (AA), respectively, in which reactants were selected to model platform molecules of biomass origin. The undesired CC hydrogenolysis activity of supported Ni catalyst, resulting in low value gaseous products, could be reined by the modification, generating silica-supported Ni2P and Ni2In active phases.

KW - Acetic acid

KW - Bio-oil conversion

KW - HDN

KW - HDO

KW - NiIn/SiO

KW - NiP/SiO

KW - Propylamine

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