A possible nanoreactor: CaFe-L(ayered)D(ouble)H(ydroxide) with intercalated cinnamate derivatives

D. Srankó, Sz Muráth, M. Sipiczki, M. Szabó, Á. Kukovecz, Z. Kónya, P. Sipos, I. Pálinkó

Research output: Chapter in Book/Report/Conference proceedingConference contribution

2 Citations (Scopus)

Abstract

The synthesis and characterisation of various organic-inorganic nanohybrids are reported in this contribution. The host material was Ca3Fe-LDH prepared by the co-precipitation method. Ecinnamate, E-4-nitrocinnamate or E-2,5-difluorocinnamate anions were the guests. Successful intercalation occurred through the introduction of the guest anion into the interlayer region of the host materials with the dehydration-rehydration method. The obtained nanohybrids were studied by powder X-ray diffractometry (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray fluorescence (EDX) coupled to the SEM instrument and infrared spectroscopy (IR). These methods were used on one hand to prove that intercalation was successful and for the characterisation of the substances on the other. Molecular modelling was used for visualising the possible spatial arrangement of the organic anions.

Original languageEnglish
Title of host publicationMaterials Science Forum
Pages65-70
Number of pages6
Volume730-732
DOIs
Publication statusPublished - 2013
Event6th International Materials Symposium, Materiais 2011 - Guimaraes, Portugal
Duration: Apr 18 2011Apr 20 2011

Publication series

NameMaterials Science Forum
Volume730-732
ISSN (Print)02555476

Other

Other6th International Materials Symposium, Materiais 2011
CountryPortugal
CityGuimaraes
Period4/18/114/20/11

Fingerprint

Cinnamates
Nanoreactors
Anions
Negative ions
Intercalation
anions
Derivatives
intercalation
Scanning electron microscopy
scanning electron microscopy
Molecular modeling
Coprecipitation
Dehydration
dehydration
Powders
X ray diffraction analysis
Infrared spectroscopy
interlayers
x rays
Fluorescence

Keywords

  • CaFe-LDH
  • E-2,5-difluoro-cinnamate
  • E-4-nitrocinnamate
  • E-cinnamate
  • Intercalation
  • Structural characterisation

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering
  • Mechanics of Materials

Cite this

Srankó, D., Muráth, S., Sipiczki, M., Szabó, M., Kukovecz, Á., Kónya, Z., ... Pálinkó, I. (2013). A possible nanoreactor: CaFe-L(ayered)D(ouble)H(ydroxide) with intercalated cinnamate derivatives. In Materials Science Forum (Vol. 730-732, pp. 65-70). (Materials Science Forum; Vol. 730-732). https://doi.org/10.4028/www.scientific.net/MSF.730-732.65

A possible nanoreactor : CaFe-L(ayered)D(ouble)H(ydroxide) with intercalated cinnamate derivatives. / Srankó, D.; Muráth, Sz; Sipiczki, M.; Szabó, M.; Kukovecz, Á.; Kónya, Z.; Sipos, P.; Pálinkó, I.

Materials Science Forum. Vol. 730-732 2013. p. 65-70 (Materials Science Forum; Vol. 730-732).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Srankó, D, Muráth, S, Sipiczki, M, Szabó, M, Kukovecz, Á, Kónya, Z, Sipos, P & Pálinkó, I 2013, A possible nanoreactor: CaFe-L(ayered)D(ouble)H(ydroxide) with intercalated cinnamate derivatives. in Materials Science Forum. vol. 730-732, Materials Science Forum, vol. 730-732, pp. 65-70, 6th International Materials Symposium, Materiais 2011, Guimaraes, Portugal, 4/18/11. https://doi.org/10.4028/www.scientific.net/MSF.730-732.65
Srankó D, Muráth S, Sipiczki M, Szabó M, Kukovecz Á, Kónya Z et al. A possible nanoreactor: CaFe-L(ayered)D(ouble)H(ydroxide) with intercalated cinnamate derivatives. In Materials Science Forum. Vol. 730-732. 2013. p. 65-70. (Materials Science Forum). https://doi.org/10.4028/www.scientific.net/MSF.730-732.65
Srankó, D. ; Muráth, Sz ; Sipiczki, M. ; Szabó, M. ; Kukovecz, Á. ; Kónya, Z. ; Sipos, P. ; Pálinkó, I. / A possible nanoreactor : CaFe-L(ayered)D(ouble)H(ydroxide) with intercalated cinnamate derivatives. Materials Science Forum. Vol. 730-732 2013. pp. 65-70 (Materials Science Forum).
@inproceedings{ded3100437c4425181b45691ee0a10e7,
title = "A possible nanoreactor: CaFe-L(ayered)D(ouble)H(ydroxide) with intercalated cinnamate derivatives",
abstract = "The synthesis and characterisation of various organic-inorganic nanohybrids are reported in this contribution. The host material was Ca3Fe-LDH prepared by the co-precipitation method. Ecinnamate, E-4-nitrocinnamate or E-2,5-difluorocinnamate anions were the guests. Successful intercalation occurred through the introduction of the guest anion into the interlayer region of the host materials with the dehydration-rehydration method. The obtained nanohybrids were studied by powder X-ray diffractometry (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray fluorescence (EDX) coupled to the SEM instrument and infrared spectroscopy (IR). These methods were used on one hand to prove that intercalation was successful and for the characterisation of the substances on the other. Molecular modelling was used for visualising the possible spatial arrangement of the organic anions.",
keywords = "CaFe-LDH, E-2,5-difluoro-cinnamate, E-4-nitrocinnamate, E-cinnamate, Intercalation, Structural characterisation",
author = "D. Srank{\'o} and Sz Mur{\'a}th and M. Sipiczki and M. Szab{\'o} and {\'A}. Kukovecz and Z. K{\'o}nya and P. Sipos and I. P{\'a}link{\'o}",
year = "2013",
doi = "10.4028/www.scientific.net/MSF.730-732.65",
language = "English",
isbn = "9783037854938",
volume = "730-732",
series = "Materials Science Forum",
pages = "65--70",
booktitle = "Materials Science Forum",

}

TY - GEN

T1 - A possible nanoreactor

T2 - CaFe-L(ayered)D(ouble)H(ydroxide) with intercalated cinnamate derivatives

AU - Srankó, D.

AU - Muráth, Sz

AU - Sipiczki, M.

AU - Szabó, M.

AU - Kukovecz, Á.

AU - Kónya, Z.

AU - Sipos, P.

AU - Pálinkó, I.

PY - 2013

Y1 - 2013

N2 - The synthesis and characterisation of various organic-inorganic nanohybrids are reported in this contribution. The host material was Ca3Fe-LDH prepared by the co-precipitation method. Ecinnamate, E-4-nitrocinnamate or E-2,5-difluorocinnamate anions were the guests. Successful intercalation occurred through the introduction of the guest anion into the interlayer region of the host materials with the dehydration-rehydration method. The obtained nanohybrids were studied by powder X-ray diffractometry (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray fluorescence (EDX) coupled to the SEM instrument and infrared spectroscopy (IR). These methods were used on one hand to prove that intercalation was successful and for the characterisation of the substances on the other. Molecular modelling was used for visualising the possible spatial arrangement of the organic anions.

AB - The synthesis and characterisation of various organic-inorganic nanohybrids are reported in this contribution. The host material was Ca3Fe-LDH prepared by the co-precipitation method. Ecinnamate, E-4-nitrocinnamate or E-2,5-difluorocinnamate anions were the guests. Successful intercalation occurred through the introduction of the guest anion into the interlayer region of the host materials with the dehydration-rehydration method. The obtained nanohybrids were studied by powder X-ray diffractometry (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray fluorescence (EDX) coupled to the SEM instrument and infrared spectroscopy (IR). These methods were used on one hand to prove that intercalation was successful and for the characterisation of the substances on the other. Molecular modelling was used for visualising the possible spatial arrangement of the organic anions.

KW - CaFe-LDH

KW - E-2,5-difluoro-cinnamate

KW - E-4-nitrocinnamate

KW - E-cinnamate

KW - Intercalation

KW - Structural characterisation

UR - http://www.scopus.com/inward/record.url?scp=84870763714&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84870763714&partnerID=8YFLogxK

U2 - 10.4028/www.scientific.net/MSF.730-732.65

DO - 10.4028/www.scientific.net/MSF.730-732.65

M3 - Conference contribution

AN - SCOPUS:84870763714

SN - 9783037854938

VL - 730-732

T3 - Materials Science Forum

SP - 65

EP - 70

BT - Materials Science Forum

ER -