A possible nanoreactor: CaFe-L(ayered)D(ouble)H(ydroxide) with intercalated cinnamate derivatives

D. Srankó, Sz Muráth, M. Sipiczki, M. Szabó, A. Kukovecz, Z. Kónya, P. Sipos, I. Pálinkó

Research output: Chapter in Book/Report/Conference proceedingConference contribution

2 Citations (Scopus)

Abstract

The synthesis and characterisation of various organic-inorganic nanohybrids are reported in this contribution. The host material was Ca3Fe-LDH prepared by the co-precipitation method. Ecinnamate, E-4-nitrocinnamate or E-2,5-difluorocinnamate anions were the guests. Successful intercalation occurred through the introduction of the guest anion into the interlayer region of the host materials with the dehydration-rehydration method. The obtained nanohybrids were studied by powder X-ray diffractometry (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray fluorescence (EDX) coupled to the SEM instrument and infrared spectroscopy (IR). These methods were used on one hand to prove that intercalation was successful and for the characterisation of the substances on the other. Molecular modelling was used for visualising the possible spatial arrangement of the organic anions.

Original languageEnglish
Title of host publicationAdvanced Materials Forum VI
Pages65-70
Number of pages6
DOIs
Publication statusPublished - Jan 1 2013
Event6th International Materials Symposium, Materiais 2011 - Guimaraes, Portugal
Duration: Apr 18 2011Apr 20 2011

Publication series

NameMaterials Science Forum
Volume730-732
ISSN (Print)0255-5476

Other

Other6th International Materials Symposium, Materiais 2011
CountryPortugal
CityGuimaraes
Period4/18/114/20/11

Keywords

  • CaFe-LDH
  • E-2,5-difluoro-cinnamate
  • E-4-nitrocinnamate
  • E-cinnamate
  • Intercalation
  • Structural characterisation

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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  • Cite this

    Srankó, D., Muráth, S., Sipiczki, M., Szabó, M., Kukovecz, A., Kónya, Z., Sipos, P., & Pálinkó, I. (2013). A possible nanoreactor: CaFe-L(ayered)D(ouble)H(ydroxide) with intercalated cinnamate derivatives. In Advanced Materials Forum VI (pp. 65-70). (Materials Science Forum; Vol. 730-732). https://doi.org/10.4028/www.scientific.net/MSF.730-732.65