A one-step Regioselective construction of the steroid skeleton by lewis acid catalyzed high pressure diels-alder reaction

E. Gács-Baitz, Lucio Minuti, Roberta Selvaggi, Aldo Taticchi

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The one-step regioselective construction of the steroid skeleton by high pressure EtAlC12 catalyzed Diels-Alder reaction of 3-methyl-2-cyclopenten-1-one with a 1-ethenyl-hexahydr naphthalene is described. Structure analysis of the reaction products by NMR spectroscopy is presented.

Original languageEnglish
Pages (from-to)91-95
Number of pages5
JournalNatural Product Letters
Volume2
Issue number2
DOIs
Publication statusPublished - May 1 1993

Fingerprint

Lewis Acids
naphthalene
Cycloaddition Reaction
Reaction products
Skeleton
Nuclear magnetic resonance spectroscopy
steroids
skeleton
nuclear magnetic resonance spectroscopy
Magnetic Resonance Spectroscopy
Steroids
Pressure
cyclopentenone
cycloaddition reactions
Lewis acids

Keywords

  • 3-methyl-2-cyclopenten-1-one
  • Diels-Alder reaction
  • high pressure
  • NMR analysis
  • steroids

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

A one-step Regioselective construction of the steroid skeleton by lewis acid catalyzed high pressure diels-alder reaction. / Gács-Baitz, E.; Minuti, Lucio; Selvaggi, Roberta; Taticchi, Aldo.

In: Natural Product Letters, Vol. 2, No. 2, 01.05.1993, p. 91-95.

Research output: Contribution to journalArticle

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