A new, three-component cobalt-catalysed domino reaction leading to ferrocenyl-tetrahydro-4(1H)-pyrimidinone derivatives

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Abstract

The use of N-(alkyl/arylmethyl)-ferrocenylimines as ketene scavengers in the cobalt-catalysed carbonylation of ethyl diazoacetate resulted in the formation of tetrahydro-4(1H)-pyrimidinones as the main products. The structures of the new compounds were determined by various NMR techniques including 2D measurements. In some cases, the stereochemistry was proved by X-ray crystallography.

Original languageEnglish
Pages (from-to)131-138
Number of pages8
JournalJournal of Organometallic Chemistry
Volume718
DOIs
Publication statusPublished - Nov 1 2012

Keywords

  • Carbonylation
  • Cobalt
  • Domino reactions
  • Ferrocenes
  • Schiff bases

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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